Cargo config env vars not working, it seems?

I'm trying to get ash (vulkan bindings) to work (on macOS). You're supposed give it environment variables, as explained in that link, and shown below. My super-small test program won't run if I put them in .cargo/config.toml, but it will work if I set them in the shell. Am I doing something wrong with the Cargo config?

cat .cargo/config.toml:

[env]
VULKAN_SDK = "/Users/rob/Dev/VulkanSDK/1.3.275.0/macOS"
DYLD_FALLBACK_LIBRARY_PATH = "/Users/rob/Dev/VulkanSDK/1.3.275.0/macOS/lib"
VK_ICD_FILENAMES = "/Users/rob/Dev/VulkanSDK/1.3.275.0/macOS/share/vulkan/icd.d/MoltenVK_icd.json"
VK_LAYER_PATH = "/Users/rob/Dev/VulkanSDK/1.3.275.0/macOS/share/vulkan/explicit_layer.d"

When I try to run it:

% cargo run -p bambu_ui --example hello_world
   warning: /MonoRepo/bambu_ui/Cargo.toml: version requirement `0.38.0+1.3.275` for dependency `ash` includes semver metadata which will be ignored, removing the metadata is recommended to avoid confusion
   [...]
  Running `target/debug/examples/hello_world`
dyld[18267]: Library not loaded: @rpath/libvulkan.1.dylib
Referenced from: <F940628B-BBD4-3CE5-85DF-1F1DD73B0270> /MonoRepo/target/debug/examples/hello_world
Reason: tried: '/MonoRepo/target/debug/build/freetype-sys-bf3d0fcfa00bf77f/out/libvulkan.1.dylib' (no such file), 
'/MonoRepo/target/debug/deps/libvulkan.1.dylib' (no such file), 
'/MonoRepo/target/debug/libvulkan.1.dylib' (no such file), 
'/Users/rob/.rustup/toolchains/stable-x86_64-apple-darwin/lib/rustlib/x86_64-apple-darwin/lib/libvulkan.1.dylib' (no such file), 
'/Users/rob/.rustup/toolchains/stable-x86_64-apple-darwin/lib/libvulkan.1.dylib' (no such file),
'/Users/rob/lib/libvulkan.1.dylib' (no such file), 
'/usr/local/lib/libvulkan.1.dylib' (no such file), 
'/usr/lib/libvulkan.1.dylib' (no such file, not in dyld cache)

But if I set the same values directly in the shell, it then runs:

% cat vulk_env 
export VULKAN_SDK=/Users/rob/Dev/VulkanSDK/1.3.275.0/macOS
export DYLD_FALLBACK_LIBRARY_PATH=${VULKAN_SDK}/lib
export VK_ICD_FILENAMES=${VULKAN_SDK}/share/vulkan/icd.d/MoltenVK_icd.json
export VK_LAYER_PATH=${VULKAN_SDK}/share/vulkan/explicit_layer.d

% source vulk_env 

% cargo run -p bambu_ui --example hello_world
warning: /MonoRepo/bambu_ui/Cargo.toml: version requirement `0.38.0+1.3.275` for dependency `ash` includes semver metadata which will be ignored, removing the metadata is recommended to avoid confusion
   Compiling ash v0.38.0+1.3.281
   Compiling ash-window v0.13.0
   Compiling bambu_ui v0.1.0 (/MonoRepo/bambu_ui)
    Finished `dev` profile [unoptimized + debuginfo] target(s) in 15.67s
    [...]
     Running `target/debug/examples/hello_world`
Application::run <-- so it ran successfully this time.

Also not sure why it keeps recompiling ash at a different version from what I specified in my Cargo.toml.

[dependencies]
ash = { version = "0.38.0+1.3.275", features = ["linked"] }

The answer lies here: